ELECTROLYTIC PARTIAL FLUORINATION OF ORGANIC-COMPOUNDS .5. ANODIC GEM-DIFLUORINATION OF DITHIOACETALS

被引：45

作者：

YOSHIYAMA, T ^{[1
]}

FUCHIGAMI, T ^{[1
]}

机构：

[1] TOKYO INST TECHNOL, DEPT ELECTR CHEM, 4259 NAGATSUTA, MIDORI KU, YOKOHAMA, KANAGAWA 227, JAPAN

来源：

CHEMISTRY LETTERS | 1992年 / 10期

关键词：

D O I：

10.1246/cl.1992.1995

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Anodic desulfurization of dithioacetals of ketones in the presence of Et3N.3HF provided the corresponding gem-difluorocompounds while dithioacetals of aromatic and aliphatic aldehydes gave gem-difluoro thioethers and monofluoro thioether, respectively.

引用

页码：1995 / 1998

页数：4

共 13 条

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[12]

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[13] GEM-DIFLUORO COMPOUNDS - A CONVENIENT PREPARATION FROM KETONES AND ALDEHYDES BY HALOGEN FLUORIDE TREATMENT OF 1,3-DITHIOLANES [J].

SONDEJ, SC ;

KATZENELLENBOGEN, JA .

JOURNAL OF ORGANIC CHEMISTRY, 1986, 51 (18) :3508-3513

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