OBSERVATION OF VIBRATIONAL-EXCITATION IN H2O PRODUCED IN THE REACTION OF OH WITH CYCLOOCTANE

被引：3

作者：

VIEGUT, TR ^{[1
]}

HOSSENLOPP, JM ^{[1
]}

机构：

[1] MARQUETTE UNIV,DEPT CHEM,MILWAUKEE,WI 53233

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1992年 / 96卷 / 18期

关键词：

D O I：

10.1021/j100197a010

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Time-resolved diode laser infrared absorption/gain spectroscopy was used to investigate vibrational energy disposal in H2O produced in the reaction of OH with cyclooctane. Persistant population inversions under multiple-collision conditions were observed while probing transitions between the 000-010, 010-020, and 010-100 vibrational states of H2O. An equilibrated rotational temperature was determined to be 500 +/- 200 K for typical reaction conditions.

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页码：7172 / 7175

页数：4

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