ELECTRON-PARAMAGNETIC RESONANCE STUDY OF THE REACTION OF AG ATOMS WITH C60 IN CYCLOHEXANE ON A ROTATING CRYOSTAT

被引：23

作者：

HOWARD, JA

TOMIETTO, M

WILKINSON, DA

机构：

[1] Steacie Institute for Molecular Sciences, National Research Council of Canada

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1991年 / 113卷 / 21期

关键词：

D O I：

10.1021/ja00021a007

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An EPR study at 175 K of the paramagnetic products from reaction of vapor-deposited Ag-107 atoms with vapor-deposited C60 at 77 K, matrix isolated in cyclohexane, revealed the presence of a species with the isotropic magnetic parameters a107 = 228 +/- 5 MHz and g = 1.9913 +/- 0.0005. These parameters are consistent with the formation of the mononuclear silver(0) complex, AgC60, which has most of the unpaired spin on the C60 ligand.

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页码：7870 / 7872

页数：3

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