FLUOROCARBON COMPLEXES OF RHODIUM CONTAINING TRIPHENYLSTIBINE AND TRIPHENYLARSINE

被引：45

作者：

MAGUE, JT

WILKINSO.G

机构：

[1] Department of Chemistry, Imperial College, London, England

[2] Department of Chemistry, Tulane University, New Orleans

来源：

INORGANIC CHEMISTRY | 1968年 / 7卷 / 03期

关键词：

D O I：

10.1021/ic50061a032

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Tris(triphenylstibine)chlororhodium(I) reacts readily with tetrafluoroethylene to produce the complex RhCl(C2F4)(Sb-(C6H5)3)2. With hexafluorobut-2-yne, the complexes RhCl(C4F6)(Sb(C6H5)3)3 and RhCUC8F12)(Sb(C6H5)3)2 are formed. The latter five-coordinate complex contains a rhodiacyclopentadiene ring and being coordinatively unsaturated for rhodium-(III) readily forms adducts with donor molecules such as carbon monoxide, phosphorus trifluoride, and pyridine. An analogous rhodiacyclopentadiene derivative is formed from tris(triphenylarsine)chlororhodiuin(I) and hexafluorobut-2-yne. © 1968, American Chemical Society. All rights reserved.

引用

页码：542 / &

共 16 条

[1] ADDITION REACTIONS OF TRIS(TRIPHENYLPHOSPHINE)CHLORORHODIUM(I) - HYDRIDO- ALKYL AND ACYL COMPLEXES - CARBON MONOXIDE INSERTION AND DECARBONYLATION REACTIONS
BAIRD, MC
MAGUE, JT
OSBORN, JA
WILKINSON, G
[J]. JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1967, (08): : 1347 - +
[2] BICHLER REJ, 1967, INORG NUCL CHEM LETT, V3, P71
[3] BOSTON JL, 1963, J CHEM SOC, P3468
[4] RHODIUM(1) AND RHODIUM(3) CARBONYL COMPLEXES CONTAING TERTIARY PHOSPHINES OR TERTIARY ARSINES AND HALOGEN FORMED BY DECARBONYLATION OF ALCOHOLS AND BY DIRECT USE OF CARBON MONIXIDE
CHATT, J
SHAW, BL
[J]. JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1966, (10): : 1437 - &
[5] CHEMISTRY OF METAL HYDRIDES .2. SPECTROSCOPIC STUDIES OF FLUOROVINYLPLATINUM (2) DERIVATIVES
CLARK, HC
TSANG, WS
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (03) : 533 - +
[6] ACETYLENE COMPLEXES OF IRIDIUM AND RHODIUM
COLLMAN, JP
KANG, JW
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (04) : 844 - &
[7] THE TRIMERIZATION OF HEXAFLUORO-2-BUTYNE
HARRIS, JF
HARDER, RJ
SAUSEN, GN
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1960, 25 (04) : 633 - 634
[8] INTERACTION OF PERFLUOROBUTADIENE WITH IRON AND COBALT CARBONYLS
HUNT, RL
ROUNDHIL.DM
WILKINSO.G
[J]. JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1967, (06): : 982 - &
[9] TRIFLUOROPHOSPHINE COMPLEXES OF TRANSITION METALS
KRUCK, T
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1967, 6 (01) : 53 - +
[10] TRIS(TRIPHENYLARSINE)- AND TRIS(TRIPHENYLSTIBINE)-CHLORORHODIUM(I) COMPLEXES AND THEIR REACTIONS WITH HYDROGEN OLEFINS AND OTHER REAGENTS
MAGUE, JT
WILKINSO.G
[J]. JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1966, (12): : 1736 - &

← 1 2 →