THEORY OF ENHANCED LIGHT-SCATTERING FROM MOLECULES ADSORBED AT THE METAL-SOLUTION INTERFACE

被引：171

作者：

GERSTEN, JI

BIRKE, RL

LOMBARDI, JR

机构：

[1] CUNY CITY COLL,DEPT PHYS,NEW YORK,NY 10031

[2] CUNY CITY COLL,DEPT CHEM,NEW YORK,NY 10031

来源：

PHYSICAL REVIEW LETTERS | 1979年 / 43卷 / 02期

关键词：

D O I：

10.1103/PhysRevLett.43.147

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

We present a theory to explain the anomalous enhancement of light scattering from molecules adsorbed at a metal-solution interface. It is found that tunneling of electrons between a surface molecule and the metal induces a resonance at a point in the vicinity of the Fermi surface. A dynamical equilibrium due to photoionization and recombination stabilizes the system near resonance. © 1979 The American Physical Society.

引用

页码：147 / 150

页数：4

共 8 条

[1] ANOMALOUSLY INTENSE RAMAN-SPECTRA OF PYRIDINE AT A SILVER ELECTRODE
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[7] SELF-CONSISTENT MODEL OF HYDROGEN CHEMISORPTION
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[8] LASER RAMAN-SPECTROSCOPY AT SURFACE OF A COPPER ELECTRODE
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