EFFECT OF DRYING OF SOILS ON THE ADSORPTION AND LEACHING OF PHOSPHATE AND 2,4-DICHLOROPHENOXYACETIC ACID

被引:12
作者
BASKARAN, S [1 ]
BOLAN, NS [1 ]
RAHMAN, A [1 ]
TILLMAN, RW [1 ]
MACGREGOR, AN [1 ]
机构
[1] RUAKURA AGR CTR,WEED RES GRP,HAMILTON,NEW ZEALAND
来源
AUSTRALIAN JOURNAL OF SOIL RESEARCH | 1994年 / 32卷 / 03期
关键词
PHOSPHATE; 2,4-D; SOIL DRYING; ADSORPTION; KINETICS; LEACHING;
D O I
10.1071/SR9940491
中图分类号
S15 [土壤学];
学科分类号
0903 ; 090301 ;
摘要
Surface samples of an allophanic (Patua silt loam) and a non-allophanic (Tokomaru silt loam) soil were used to examine the effects of drying on the adsorption and leaching of phosphate and 2,4-dichlorophenoxyacetic acid (2,4-D). Phosphate and 2,4-D adsorption isotherms and adsorption kinetics were determined for field-moist, air-dried and oven-dried soil samples using KH2PO4 and C-14 labelled 2,4-D. In a separate experiment, the leaching of a pulse of phosphate or 2,4-D was examined using soil columns. The Patua silt loam adsorbed 4-7 times more phosphate and 2,4-D than the Tokomaru silt loam. Compared with field-moist soil, both air-dried and oven-dried soil increased (2-5 times) the adsorption of phosphate, and oven-dried soil decreased the adsorption of 2,4-D. The adsorption kinetics indicated that there was no effect of drying on the rate of adsorption of either phosphate or 2,4-D. In column experiments, there was less leaching of phosphate and 2,4-D from the Patua soil than from the Tokomaru soil. In both soils, there was no effect of drying on the leaching of phosphate, whereas oven-drying increased the leaching of 2,4-D. Solubilization of organic matter during drying increased the accessibility of P to adsorption sites on the mineral surface and thereby increased the adsorption, whereas the water-soluble organic matter bound 2,4-D and thereby decreased the apparent adsorption onto soil and increased leaching.
引用
收藏
页码:491 / 502
页数:12
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