CHEMISTRY OF PYRIDINE .7. TETRAHYDROPYRIDINES FROM REACTION OF PYRIDINE N-OXIDES WITH MERCAPTANS IN ACETIC ANHYDRIDE

被引：20

作者：

HERSHENS.FM

BAUER, L

机构：

[1] Department of Chemistry, College of Pharmacy, University of Illinois at the Medical Center, Chicago

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1969年 / 34卷 / 03期

关键词：

D O I：

10.1021/jo01255a039

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A number of solids isolated from the reaction of pyridine N-oxides with mercaptans in acetic anhydride were shown to be 1-acetyl-1,2,3,6-tetrahydropyridines. One feature common to these compounds was that a sulfide group was attached to the β sp3 ring carbon while both the α positions on the ring were substituted by either sulfide or acetoxy groups. The formation of these products is discussed in terms of the episulfonium intermediate proposed in the prior paper. © 1969, American Chemical Society. All rights reserved.

引用

页码：660 / &

共 22 条

[1] MASS SPECTROMETRY IN STRUCTURAL AND STEREOCHEMICAL PROBLEMS .142. ELECTRON IMPACT INDUCED ANALOGIES TO THERMAL ELIMINATION PROCESSES IN S-METHYL XANTHATES AND ESTERS
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[8] BUDZIKIEWICZ H, 1967, MASS SPECTROMETRY OR
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[10] CHEMISTRY OF PYRIDINE .8. STEROCHEMISTRY OF TETRAHYDROPYRIDINES ISOLATED FROM REACTION OF PYRIDINE N-OXIDES WITH MERCAPTANS IN ACETIC ANHYDRIDE
EGAN, RS
HERSHENS.FM
BAUER, L
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1969, 34 (03) : 665 - &

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