MASS SPECTRAL STUDY ON THIAZOLO[3,2-ALPHA]BENZIMIDAZOLES . STUDIES ON HETEROCYCLIC COMPOUNDS .4.

被引:23
作者
OGURA, H
ITOH, T
KIKUCHI, K
机构
[1] School of Pharmaceutical Sciences, Kitasato University, Tokyo
关键词
D O I
10.1002/jhet.5570060604
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Condensation of α‐halocarbonyl compounds and 2‐mercaptobenzimidazole gives thiazolo‐[3,2‐a]benzimidazoles. This condensation occurred at the mercapto group of the benzimidazole followed by cyclization to form the thiazole ring. This was confirmed by the examination of the mass spectra of 2‐ and 3‐methylthiazolo[3,2‐a]benzimidazoles, 2‐ and 3‐phenylthiazolo[3,2‐a]‐benzimidazoles, and their derivatives. Copyright © 1969 Journal of Heterocyclic Chemistry
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页码:797 / &
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