FORMATION, CHARACTERIZATION AND REACTIVITY OF A SELENAZA DICATION [R2SE+-N+R3] FROM N-METHYL-5H,7H-DIBENZO[B,G][1,5]SELENAZOCINE

被引:21
作者
FUJIHARA, H [1 ]
MIMA, H [1 ]
ERATA, T [1 ]
FURUKAWA, N [1 ]
机构
[1] UNIV TSUKUBA,DEPT APPL PHYS,SAKURA,IBARAKI 305,JAPAN
关键词
D O I
10.1039/c39910000098
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new heterocycle containing selenium and nitrogen atoms, N-methyl-5H,7H-dibenzo[b,g][1,5]selenazocine 1, has been synthesized; the reaction of the selenoxide of 1 with (CF3SO2)2O gave a novel selenaza dication salt which was characterized by Se-77 NMR spectroscopy, and the dication acts as an oxidizing agent.
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页码:98 / 99
页数:2
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