RADICAL CYCLIZATION OF BETA-ALLENIC HYDRAZONES - AN ASYMMETRIC APPROACH

被引：17

作者：

BERNARDHENRIET, CD ^{[1
]}

GRIMALDI, JR ^{[1
]}

HATEM, JM ^{[1
]}

机构：

[1] UNIV AIX MARSEILLE 1,CNRS,CHIM ORGAN SYNTH LAB,F-13397 MARSEILLE 20,FRANCE

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 22期

关键词：

D O I：

10.1016/S0040-4039(00)73075-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

beta-allenic hydrazones undergo hydrostannylation to afford cyclopentene derivatives and linear rearranged products depending on the substitution of the allenic and hydrazone moieties. A first example of asymmetric radical cyclization of a SAMP beta-allenic hydrazone is described.

引用

页码：3699 / 3702

页数：4

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