FORMATION OF SILICA INTERLAYERS IN ALPHA-ZIRCONIUM-TITANIUM MIXED PHOSPHATE AND PHOSPHONATE

被引：7

作者：

FARFANTORRES, EM

MAZARODRIGUEZ, J

MARTINEZLARA, M

JIMENEZLOPEZ, A

机构：

[1] Departamento de Química Inorgánica, Facultad de Ciencias, Universidad de Málaga, 29071 Málaga

来源：

SOLID STATE IONICS | 1993年 / 63-5卷

关键词：

D O I：

10.1016/0167-2738(93)90152-S

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Intercalation of a mixed zirconium-titanium hydrogen phosphate and a phosphate-phosphonate with 3-[(triethoxy)silyl]-1-propylamine, NH2(CH2)3Si(OC2H5)3, was investigated. Heating the intercalated solids at about 400-degrees-C produces the formation of silica-like species between the interlayers, resulting in a basal space of almost-equal-to 15 angstrom, in both cases. However, only for the intercalated phosphate-phosphonate an increase of the original surface area was obtained, showing that a pillared solid was formed in this case.

引用

收藏

页码：506 / 511

页数：6

相关论文

共 11 条

[1]

ALBERTI G, 1990, PILLARED LAYERED STR, P119

[2] INFRARED SPECTRA OF PHOSPHORUS COMPOUNDS [J].

DAASCH, LW ;

SMITH, DC .

ANALYTICAL CHEMISTRY, 1951, 23 (06) :853-868

[3] SYNTHESIS OF MIXED ZIRCONIUM-TITANIUM PHOSPHATES BY SOL-GEL PROCESSING [J].

FARFANTORRES, EM ;

SHAM, EL ;

MARTINEZLARA, M ;

JIMENEZLOPEZ, A .

MATERIALS RESEARCH BULLETIN, 1992, 27 (10) :1255-1262

[4] INTERCALATION AND PILLARING OF ZIRCONIUM BIS(MONOHYDROGENPHOSPHATE) WITH NH2(CH2)3SI(OC2H5)3 [J].

LI, LS ;

LIU, XS ;

GE, Y ;

LI, LY ;

KLINOWSKI, J .

JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (15) :5910-5914

[5] POROUS CHROMIA-PILLARED ALPHA-ZIRCONIUM PHOSPHATE MATERIALS PREPARED VIA COLLOID METHODS [J].

MAIRELESTORRES, P ;

OLIVERAPASTOR, P ;

RODRIGUEZCASTELLON, E ;

JIMENEZLOPEZ, A ;

TOMLINSON, AAG .

JOURNAL OF MATERIALS CHEMISTRY, 1991, 1 (05) :739-746

[6] POROUS CROSS-LINKED MATERIALS FORMED BY OLIGOMERIC ALUMINUM HYDROXIDES AND ALPHA-TIN PHOSPHATE [J].

MAIRELESTORRES, P ;

OLIVERAPASTOR, P ;

RODRIGUEZCASTELLON, E ;

JIMENEZLOPEZ, A ;

ALAGNA, L ;

TOMLINSON, AAG .

JOURNAL OF MATERIALS CHEMISTRY, 1991, 1 (03) :319-326

[7] CROSS-LINKED LAYERED MATERIALS FORMED BY INTERCALATION OF OCTAMERIC SILOXANES IN METAL(IV) HYDROGEN PHOSPHATES [J].

ROZIERE, J ;

JONES, DJ ;

CASSAGNEAU, T .

JOURNAL OF MATERIALS CHEMISTRY, 1991, 1 (06) :1081-1082

[8] THE PARTIAL HYDROLYSIS OF ETHYLTRIETHOXYSILANE [J].

SPRUNG, MM ;

GUENTHER, FO .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1955, 77 (15) :3996-4002

[9] THE PARTIAL HYDROLYSIS OF METHYLTRI-N-PROPOXYSILANE, METHYLTRIISOPROPOXYSILANE AND METHYLTRI-N-BUTOXYSILANE [J].

SPRUNG, MM ;

GUENTHER, FO .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1955, 77 (22) :6045-6047

[10]

SPRUNG MM, 1955, J AM CHEM SOC, V77, P3990, DOI 10.1021/ja01620a013