SYNTHESIS AND CHARACTERIZATION OF MIXED CYANOTHIOCYANATE AND CYANOSELENOCYANATE COMPLEXES OF BIS(CYCLOPENTADIENYL)-TITANIUM, BIS(CYCLOPENTADIENYL)-VANADIUM AND BIS(CYCLOPENTADIENYL)-CHROMIUM

被引：22

作者：

MORAN, M

FERNANDEZ, V

机构：

[1] Departamento de Química Inorgánica, Universidad Autoónoma de Madrid, Canto Blanco, Madrid

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 165卷 / 02期

关键词：

D O I：

10.1016/S0022-328X(00)94323-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complexes (η-C5H5)2Ti(CO)2 and (η-C5H5)2M, (M = V, Cr) react with (SeCN)2 to give the isoselenocyanide complexes (η-C5H5)2M(NCSe)2, (M = Ti, V, Cr), but with X(CN)2, (X = Se, S) they give the mixed complexes (η-C5H5)2M(CN)(NCX), (M = Ti, V, Cr; X = S, Se). All the compounds have been characterized by elemental analyses, magnetic moments, and IR and EPR spectra. © 1979.

引用

页码：215 / 223

页数：9

共 30 条

[1]

ADAMS DM, 1967, METAL LIGAND RELATED, pCH4

[2]

BAYLEY RA, 1971, J INORG NUCL CHEM, V33, P3206

[3]

BAYLEY RA, 1971, COORD CHEM REV, V6, P407

[4] PREPARATION AND ISOLATION OF K3[CR(NCSE)6] [J].