HEXACOORDINATION AT SILICON - THE CASE OF SILATRANES

被引：29

作者：

CARRE, F ^{[1
]}

CERVEAU, G ^{[1
]}

CHUIT, C ^{[1
]}

CORRIU, RJP ^{[1
]}

NAYYAR, NK ^{[1
]}

REYE, C ^{[1
]}

机构：

[1] UNIV MONTPELLIER 2,URA 1097,INST CHIM FINE,PL E BATAILLON,F-34095 MONTPELLIER 05,FRANCE

来源：

ORGANOMETALLICS | 1990年 / 9卷 / 07期

关键词：

D O I：

10.1021/om00157a001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

(2-(1-(Dimethylamino)ethyl)phenyl)silatrane and (8-(dimethylamino)-1-naphthyl)silatrane have been prepared in order to study the possibility of intramolecular coordination at silicon by a nucleophilic atom in the silatrane structure. The structure of the former exhibits no chelation of the NMe2 group; the geometry around the silicon atom remains trigonal bipyramidal. In contrast, the structure of the latter suggests a weak interaction between the silicon atom and the NMe2 group. © 1990, American Chemical Society. All rights reserved.

引用

页码：1989 / 1991

页数：3

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