BINUCLEAR NICKEL(II) COMPLEXES OF SCHIFF-BASES DERIVED FROM SALICYLALDEHYDES AND 1,N-DIAMINO-N'-HYDROXYALKANES (N,N' = 3,2 4,2 AND 5,3) HAVING AN ENDOGENOUS ALKOXO BRIDGE AND A PYRAZOLATO EXOGENOUS BRIDGE

被引：43

作者：

MIKURIYA, M ^{[1
]}

SASAKI, T ^{[1
]}

ANJIKI, A ^{[1
]}

IKENOUE, S ^{[1
]}

TOKII, T ^{[1
]}

机构：

[1] SAGA UNIV, FAC SCI & ENGN, DEPT CHEM, SAGA 840, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1992年 / 65卷 / 02期

关键词：

D O I：

10.1246/bcsj.65.334

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mu-Alkoxo-mu-pyrazolato-bridged binuclear nickel(II) complexes with 1,3-bis(salicylideneamino)-2-propanol (H3L(a)), 1,4-bis(salicylidenEamino)-2-butanol (H3L(b)), and 1,5-bis(salicylideneamino)-3-pentanol (H3L(c)), Ni2(L(a))(pz), Ni2(L(b))(pz), and Ni2(L(c))(pz) (pz = pyrazolate anion), have been prepared and characterized by elemental analyses, infrared and electronic spectra, and magnetic susceptibilities. The molecular structures of these complexes were determined by the single-crystal X-ray structure analyses. The planarities of the molecules were discussed in relation to the variation of the chain lengths of the Schiff bases.

引用

页码：334 / 339

页数：6

共 25 条

[1]

BERTRAND JA, 1970, INORG CHIM ACTA, V4, P192

[2]

BERTRAND JA, 1976, PROGR INORG CHEM, V21, P29

[3] MONONUCLEAR AND BINUCLEAR COMPLEXES WITH BINUCLEATING LIGANDS, INVOLVING PYRROLE, IMIDAZOLE AND SALICYLALDEHYDE DERIVATIVES [J].

BORER, LL ;

SINN, E .

INORGANICA CHIMICA ACTA, 1988, 142 (02) :197-199

[4] COPPER-COMPLEXES OF BINUCLEATING N,N'-HYDROXYALKYLDIAMINEBIS(SALICYLIDINE) LIGANDS CONTAINING A CU-O-CU BRIDGE AND AN EXOGENOUS BRIDGE [J].

BUTCHER, RJ ;

DIVEN, G ;

ERICKSON, G ;

MOCKLER, GM ;

SINN, E .

INORGANICA CHIMICA ACTA, 1986, 111 (02) :L55-L56

[5] TOWARDS A HEMOCYANIN MODEL - RELATION BETWEEN MOLECULAR AND ELECTRONIC-STRUCTURE IN BINUCLEAR COMPLEXES - EFFECT OF BRIDGING GROUP LENGTH AND ANGLE BETWEEN METAL PLANES [J].

BUTCHER, RJ ;

DIVEN, G ;

ERICKSON, G ;

MOCKLER, GM ;

SINN, E .

INORGANICA CHIMICA ACTA-BIOINORGANIC CHEMISTRY, 1986, 123 (03) :L17-L19

[6]

DAPPORTO P, 1969, J CHEM SOC CHEM COMM, P329

[7] 5-CO-ORDINATION IN NICKEL(II) COMPLEXES - CRYSTAL STRUCTURE OF HIGH-SPIN COMPLEX OF NICKEL(II) PERCHLORATE WITH NN-BIS-(2-DIETHYL-AMINOETHYL)-2-HYDROXYETHYLAMINE [J].

DAPPORTO, P .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1970, (04) :618-&

[8] SYNTHESIS, CRYSTAL-STRUCTURE, AND MAGNETIC-PROPERTIES OF A PYRAZOLATE-BRIDGED BINUCLEAR COPPER(II) COMPLEX [J].

DOMAN, TN ;

WILLIAMS, DE ;

BANKS, JF ;

BUCHANAN, RM ;

CHANG, HR ;

WEBB, RJ ;

HENDRICKSON, DN .

INORGANIC CHEMISTRY, 1990, 29 (05) :1058-1062

[9]

Frenz B. A., 1985, SDP USERS GUIDE

[10] NEUTRAL BIMETALLIC MACROCYCLIC COMPLEXES .1. INVESTIGATION OF MONOMETALLIC AND BIMETALLIC COMPLEXES OF TETRAIMINATO MACROCYCLIC COMPLEXES DERIVED FROM 1,3,5-TRIKETONES [J].

HIMMELSBACH, M ;

LINTVEDT, RL ;

ZEHETMAIR, JK ;

NANNY, M ;

HEEG, MJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (26) :8003-8011

← 1 2 3 →