SPEED-DEPENDENT T2-RELAXATION RATES OF MICROWAVE EMISSION SIGNALS

被引：12

作者：

HAEKEL, J ^{[1
]}

MADER, H ^{[1
]}

机构：

[1] UNIV KIEL,INST PHYS CHEM,CHEM PHYS ABT,W-2300 KIEL 1,GERMANY

来源：

JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER | 1991年 / 46卷 / 01期

关键词：

D O I：

10.1016/0022-4073(91)90063-V

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

We report on studies of the coherence decay for pulse-induced transient emission signals in microwave spectroscopy. The treatment of absorber-speed-dependent decay rates is extended with consideration of the dependence of the rates on the relative speed of the colliding molecules. Observation for speed-dependent rates are reported for the rotational transitions J = 2-1 of OCS and J = 1-0 of HCCF, as well as for the l-type doublet transition with J = 9 of (HCN)-N-15 in the first excited bending vibrational state. The experimental results are also compared with theoretical predictions from binary collision theories.

引用

页码：21 / 30

页数：10

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