RATE CONSTANTS OF THE REACTION BETWEEN ALKYL RADICALS AND OXYGEN AND STABLE NITROXYL RADICALS

被引:9
作者
ALEKSANDROV, AL [1 ]
PLISS, EM [1 ]
SHUVALOV, VF [1 ]
机构
[1] YAROSLAVL POLYTECH INST,YAROSLAVL,USSR
来源
BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE | 1979年 / 28卷 / 11期
关键词
D O I
10.1007/BF00951696
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The rate constants of the reaction between the alkyl radicals of hydrocarbons (R.) and of vinyl monomers (M.) and O2 and stable nitroxyl radicals[Figure not available: see fulltext.] were determined at 50‡C. The low-molecular-weight radicals react with O2 (k1) and the[Figure not available: see fulltext.] (k3) more rapidly than the M. do. For polar R. and M. k1 and k3 are close, and for the nonpolar ones k1>k3. © 1980 Plenum Publishing Corporation.
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页码:2262 / 2266
页数:5
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