RATE CONSTANTS OF THE REACTION BETWEEN ALKYL RADICALS AND OXYGEN AND STABLE NITROXYL RADICALS

被引：9

作者：

ALEKSANDROV, AL ^{[1
]}

PLISS, EM ^{[1
]}

SHUVALOV, VF ^{[1
]}

机构：

[1] YAROSLAVL POLYTECH INST,YAROSLAVL,USSR

来源：

BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE | 1979年 / 28卷 / 11期

关键词：

D O I：

10.1007/BF00951696

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The rate constants of the reaction between the alkyl radicals of hydrocarbons (R.) and of vinyl monomers (M.) and O2 and stable nitroxyl radicals[Figure not available: see fulltext.] were determined at 50‡C. The low-molecular-weight radicals react with O2 (k1) and the[Figure not available: see fulltext.] (k3) more rapidly than the M. do. For polar R. and M. k1 and k3 are close, and for the nonpolar ones k1>k3. © 1980 Plenum Publishing Corporation.

引用

页码：2262 / 2266

页数：5

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