INTRA-MOLECULAR INTERVALENCE CHARGE-TRANSFER IN BIMOLECULAR MIXED-VALENCE COMPLEXES OF METALS

被引:20
作者
GERMAN, ED
机构
[1] Institute of Electrochemistry, The Academy of Sciences, the USSR, Moscow
关键词
D O I
10.1016/0009-2614(79)80516-3
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The ellipsoidal cavity model of Kirkwood-Westheimer is extended to the case when charges are located anywhere in the cavity. Within this model the solvent reorganisation energies associated with intramolecular charge transfer are calculated and compared with experimental data. © 1979.
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页码:295 / 298
页数:4
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