MECHANISM OF CONJUGATE ADDITIONS OF DIALKYLCUPRATES TO BROMONAPHTHOQUINONES

被引：18

作者：

WIGAL, CT ^{[1
]}

GRUNWELL, JR ^{[1
]}

HERSHBERGER, J ^{[1
]}

机构：

[1] MIAMI UNIV, DEPT CHEM, OXFORD, OH 45056 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1991年 / 56卷 / 12期

关键词：

D O I：

10.1021/jo00012a002

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The correlation of bromonaphthoquinone redox potentials with reactivity toward dialkylcuprates reveals that the conjugate addition of Gilman reagents to bromojuglones proceeds via a single-electron-transfer mechanism.

引用

页码：3759 / 3761

页数：3

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