MACROBICYCLIC AMINALS

被引：1

作者：

ATKINSON, A ^{[1
]}

BAILEY, NA ^{[1
]}

FENTON, DE ^{[1
]}

HEMPSTEAD, PD ^{[1
]}

WESTWOOD, GP ^{[1
]}

机构：

[1] UNIV SHEFFIELD,DEPT CHEM,SHEFFIELD S3 7HF,S YORKSHIRE,ENGLAND

来源：

JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY | 1992年 / 12卷 / 1-4期

关键词：

MACROBICYCLIC; AMINALS; X-RAY CRYSTAL STRUCTURE; TETRAIMINE MACROCYCLES; SCHIFF BASE;

D O I：

10.1007/BF01053860

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of Schiff base macrocycles in the absence of templating cations and in non-protic and non-coordinating solvent media is reported. The reaction of pyridine-2,6-dicarboxaldehyde with the diamines 1,2-bis(2-aminophenoxy)ethane and 1,4-bis(2-aminophenoxy)butane has been found to give the corresponding macrobicyclic aminals. The chemical properties of the aminals are reported together with a preliminary study of their metal complexation reactions. The X-ray crystal structure of the aminal derived from pyridine-2,6-dicarboxaldehyde and 1,2-bis(2-aminophenoxy)ethane has been determined and verifies the macrobicyclic nature of the product.

引用

页码：175 / 186

页数：12

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