THE SYNTHESIS AND CHARACTERIZATION OF RADICAL-CATION SALTS OF BIS(ETHYLENEDITHIO)TETRASELENAFULVALENE

被引：24

作者：

MONTGOMERY, LK

BURGIN, T

HUFFMAN, JC

CARLSON, KD

DUDEK, JD

YACONI, GA

MEGNA, LA

MOBLEY, PR

KWOK, WK

WILLIAMS, JM

SCHIRBER, JE

OVERMYER, DL

REN, J

ROVIRA, C

WHANGBO, MH

机构：

[1] ARGONNE NATL LAB,DIV CHEM,ARGONNE,IL 60439

[2] ARGONNE NATL LAB,DIV MAT SCI,ARGONNE,IL 60439

[3] SANDIA NATL LABS,ALBUQUERQUE,NM 87185

[4] N CAROLINA STATE UNIV,DEPT CHEM,RALEIGH,NC 27695

来源：

SYNTHETIC METALS | 1993年 / 56卷 / 01期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0379-6779(93)90378-A

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Four 2:1 radical cation salts (SbF6, CF3SO3, GaCl4, Cu[N(CN)2]Br) of bis(ethylenedithio)tetraselenafulvalene (BETS) have been prepared and scrutinized by X-ray crystallography, DC resistivity measurements (300-10K), rf penetration depth experiments (0.5K), pressure studies (0.5-5kbar, 4K), and tight-binding band calculations. The salts are kappa-phase, and three are metallic to low temperatures. Kappa-(BETS)2 Cu[N(CN)2]Br is isostructural with kappa-(ET)2 Cu[N(CN)2]Br.

引用

页码：2090 / 2095

页数：6

共 12 条

[1] COMPETITION BETWEEN SUPERCONDUCTIVITY AND SPIN-DENSITY WAVES IN AN ORGANIC CONDUCTOR, BIS-TETRAMETHYLTETRASELENAFULVALENIUM HEXAFLUOROPHOSPHATE
AZEVEDO, LJ
SCHIRBER, JE
WILLIAMS, JM
BENO, MA
STEPHENS, DR
[J]. PHYSICAL REVIEW B, 1984, 30 (03): : 1570 - 1572
[2] TEMPERATURE AND MAGNETIC-FIELD DEPENDENCE OF SUPERCONDUCTING PENETRATION DEPTH IN PURE AND IMPURE ALUMINUM SINGLE-CRYSTALS
BEHROOZI, F
GARFUNKEL, MP
ROGAN, FH
WILKINSON, GA
[J]. PHYSICAL REVIEW B, 1974, 10 (07) : 2756 - 2763
[3] ISHIGURO T, 1990, ORGANIC SUPERCONDUCT, P258
[4] KATO R, 1991, SYNTHETIC MET, V41, P2093
[5] A NEW AMBIENT-PRESSURE ORGANIC SUPERCONDUCTOR, KAPPA-(ET)2CU[N(CN)2]BR, WITH THE HIGHEST TRANSITION-TEMPERATURE YET OBSERVED (INDUCTIVE ONSET TC = 11.6 K, RESISTIVE ONSET = 12.5 K)
KINI, AM
GEISER, U
WANG, HH
CARLSON, KD
WILLIAMS, JM
KWOK, WK
VANDERVOORT, KG
THOMPSON, JE
STUPKA, DL
JUNG, D
WHANGBO, MH
[J]. INORGANIC CHEMISTRY, 1990, 29 (14) : 2555 - 2557
[6] SOLID HELIUM PRESSURE GENERATION TECHNIQUE
SCHIRBER, JE
[J]. CRYOGENICS, 1970, 10 (05) : 418 - &
[7] URAYAMA H, 1988, CHEM LETT, V55
[8] FROM SEMICONDUCTOR SEMICONDUCTOR TRANSITION (42K) TO THE HIGHEST-12.5 K ORGANIC SUPERCONDUCTOR, KAPPA-(ET)2CU[N(CN)2]CL
WILLIAMS, JM
KINI, AM
WANG, HH
CARLSON, KD
GEISER, U
MONTGOMERY, LK
PYRKA, GJ
WATKINS, DM
KOMMERS, JM
BORYSCHUK, SJ
CROUCH, AVS
KWOK, WK
SCHIRBER, JE
OVERMYER, DL
JUNG, D
WHANGBO, MH
[J]. INORGANIC CHEMISTRY, 1990, 29 (18) : 3272 - 3274
[9] WILLIAMS JM, 1992, ORGANIC SUPERCONDUCT, P66
[10] WILLIAMS JM, 1992, ORGANIC SUPERCONDUCT, pCH8

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