SYNTHESIS AND STRUCTURE OF THE FIRST OLIGOMERIC CYCLIC DIMETHYLSILYL-SUBSTITUTED CARBODIIMIDE

被引：37

作者：

KIENZLE, A

OBERMEYER, A

RIEDEL, R

ALDINGER, F

SIMON, A

机构：

[1] TH DARMSTADT,FACHGEBIET DISPERSE FESTSTOFFE,FACHBEREICH MAT WISSENSCH,D-64295 DARMSTADT,GERMANY

[2] MAX PLANCK INST MET RES,INST WERKSTOFFWISSENSCH,PULVERMET LAB,D-70569 STUTTGART 80,GERMANY

[3] UNIV STUTTGART,INST ANORGAN CHEM,D-70569 STUTTGART 80,GERMANY

[4] MAX PLANCK INST FESTKORPERFORSCH,D-70569 STUTTGART 80,GERMANY

来源：

CHEMISCHE BERICHTE | 1993年 / 126卷 / 12期

关键词：

CARBODIIMIDE; SILYL; STRUCTURE; PRECURSOR;

D O I：

10.1002/cber.19931261202

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New oligomeric cyclic silylcarbodiimides 1-3 are synthesised by the reaction dichlorosilanes with cyanamide. From the resulting reaction mixture with dichloro-dimethylsilane the tetrameric compound of the hypothetical [(CH3)(2)Si=N-CN] is isolated. In this molecule sixteen atoms build a nearly planar ring structure with a special steric arrangement of the groups. This oligomeric silylcarbodiimides present a new kind of precursors for the pyrolytic synthesis of ceramics in the ternary system SiCN.

引用

页码：2569 / 2571

页数：3

共 13 条

[1] CRYSTAL AND MOLECULAR-STRUCTURE OF TRISILYLAMINE AT 115-K [J].

BARROW, MJ ;

EBSWORTH, EAV .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (04) :563-565

[2] ROTATION-VIBRATION SPECTRA OF DIATOMIC AND SIMPLE POLYATOMIC MOLECULES WITH LONG ABSORBING PATHS .9. THE SPECTRA OF THE HCN AND DCN MOLECULES FROM 2.5-MU TO 0.5-MU [J].

DOUGLAS, AE ;

SHARMA, D .

JOURNAL OF CHEMICAL PHYSICS, 1953, 21 (03) :448-458

[3]

GLIDEWELL C, 1970, J MOL STRUCT, V6, P231, DOI 10.1016/0022-2860(70)80018-7

[4]

KIENZLE A, 1993, JUN JAHR TAG DTSCH G

[5]

OBERMEYER A, UNPUB

[6]

PAULING L, 1976, NATURE CHEM BOND

[7] SILYCARBODIIMIDE .4. SILA-POLYCARBODIIMIDE [J].

PUMP, J ;

ROCHOW, EG .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1964, 330 (1-2) :101-106

[8] SYNTHESIS OF DENSE SILICON-BASED CERAMICS AT LOW-TEMPERATURES [J].

RIEDEL, R ;

PASSING, G ;

SCHONFELDER, H ;

BROOK, RJ .

NATURE, 1992, 355 (6362) :714-717

[9]

Riedel R., 1989, Journal of the European Ceramic Society, V5, P113, DOI 10.1016/0955-2219(89)90018-6

[10]

RIEDEL R, 1991, CONCISE ENCY ADV CER, P299

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