PREFERENTIAL SOLVATION IN MIXED-SOLVENTS PART .7. BINARY-MIXTURES OF WATER AND ALKANOLAMINES

被引：28

作者：

MARCUS, Y

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS | 1995年 / 91卷 / 03期

关键词：

D O I：

10.1039/ft9959100427

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The inverse Kirkwood-Buff integral method is applied to mixtures of water with ethanolamine, diethanolamine and triethanolamine at 0, 25 and 40 degrees C. Preferential solvation in these systems is deduced from these integrals and shown over the entire composition range for the 0 degrees C data, and the trends at higher temperatures are discussed. In these systems the mutual interactions of the components are stronger than the self-interactions.

引用

页码：427 / 430

页数：4

共 21 条

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