SYNTHESIS AND CHARACTERIZATION OF SILVER(I) NITRATE COMPLEXES WITH 2-CYANO-PYRIDINE, 3-CYANO-PYRIDINE AND 4-CYANO-PYRIDINE AND ANILINES

被引：6

作者：

AHUJA, IS ^{[1
]}

TRIPATHI, S ^{[1
]}

YADAVA, CL ^{[1
]}

机构：

[1] KAMLA NEHRU INST PHYS & SOCIAL SCI,DEPT CHEM,SULTANPUR 228118,INDIA

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1990年 / 20卷 / 02期

关键词：

D O I：

10.1080/00945719008048126

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Coordination compounds formed by the interaction of silver(i) nitrate with 2-, 3- and 4-cyano- pyridines and anilines have been prepared and characterized on the basis of analytical data, molar conductances and infrared spectral measurements down to 200 om -1 in the solid state. The complexes isolated are Ag(2-cyanopyridine)NO3 and AgL2NO3, where L = 3- or 4- cyanopyridine, 2-, 3- or 4-cyano- aniline. Molar conductance measurements indicate that these complexes are non-electrolytes in ethanol but 1:1 electrolytes in aqueous solutions. Infrared spectral studies show that (i) the cyano-pyridines and anilines, though potentially bidentate ligands, act as monodentate ones bonding via the pyridine ring nitrogen (cyanopyridines) or NH2 nitrogen (cyanoanilines) and (ii) the nitrate groups are present as terminally bonded monodentate ligands in all the compounds except in the 2-cyanopyridine complex which is. © 1990, Taylor & Francis Group, LLC. All rights reserved.

引用

页码：189 / 198

页数：10

共 27 条

[1] STRUCTURAL ASPECTS OF CO-ORDINATED NITRATE GROUPS [J].

ADDISON, CC ;

LOGAN, N ;

WALLWORK, SC ;

GARNER, CD .

QUARTERLY REVIEWS, 1971, 25 (02) :289-&

[2]

AHUJA IS, 1976, SPECTROCHIM ACTA A, V32, P547, DOI 10.1016/0584-8539(76)80115-8

[3] PREPARATION AND PROPERTIES OF SOME ANILINE COMPLEXES OF METAL(2) SULPHATES AND NITRATES [J].

AHUJA, IS ;

BROWN, DH ;

NUTTALL, RH ;

SHARP, DWA .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1966, (07) :938-&

[4]

AHUJA IS, 1982, INDIAN J CHEM A, V21, P936

[5] SOME NEUTRAL 3-COORDINATE COMPLEXES OF MERCURY(II) [J].

AHUJA, IS ;

YADAVA, CL ;

TRIPATHI, S .

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1988, 18 (05) :433-438

[6] 2-CYANOPYRIDINE, 3-CYANOPYRIDINE AND 4-CYANOPYRIDINE COMPLEXES WITH SOME ZINC(II), CADMIUM(II) AND MERCURY(II) SALTS [J].

AHUJA, IS ;

SINGH, R .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1974, 36 (07) :1505-1513

[7] PREPARATION AND SPECTROSCOPIC PROPERTIES OF SOME ANILINE COMPLEXES OF TRANSITION METAL HALIDES [J].

AHUJA, IS ;

BROWN, DH ;

NUTTALL, RH ;

SHARP, DWA .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1965, 27 (05) :1105-&

[8] STRUCTURAL INFORMATION ON SILVER(I), ZINC(II) AND CADMIUM(II) NITRATE COMPLEXES WITH 1,10-PHENANTHROLINE, 2,2'-BIPYRIDINE AND 2,2'-BIPYRIDINE N,N'-DIOXIDE FROM THEIR INFRARED-SPECTRA [J].

AHUJA, IS ;

SINGH, R ;

RAI, CP .

JOURNAL OF MOLECULAR STRUCTURE, 1978, 49 (01) :201-205

[9] PREPARATION AND SPECTROSCOPIC PROPERTIES OF SOME COMPLEXES FORMED BETWEEN TRANSITION METAL HALIDES AND SUBSTITUTED ANILINES [J].

AHUJA, IS ;

BROWN, DH ;

NUTTALL, RH ;

SHARP, DWA .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1965, 27 (07) :1625-&

[10] STRUCTURAL INVESTIGATIONS OF METAL NITRATE COMPLEXES .1. CRYSTAL AND MOLECULAR STRUCTURE OF BIS[DINITRATOBIS(PYRIDINE)COPPER(II)]-PYRIDINE [CU(NO3)2(PY)2]2,PY [J].

CAMERON, AF ;

FORREST, KP ;

TAYLOR, DW ;

NUTTALL, RH .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1971, (15) :2492-&

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