REACTION OF METAL FREE BU3SN- GENERATED FROM BU3SNSIME3-R4NX WITH AN ARYL OR VINYL HALIDE

被引：38

作者：

MORI, M

KANETA, N

ISONO, N

SHIBASAKI, M

机构：

[1] Faculty of Pharmaceutical Sciences, Hokkaido University, Sapporo

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 43期

关键词：

BU3SNSIME3; BU3SN-R4N+; METAL FREE STANNYL ANION; CYCLIZATION; ARYL OR VINYL ANION;

D O I：

10.1016/0040-4039(91)80773-Y

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Metal free stannyl anion generated from Bu3SnSiMe3 and R4NX in DMF reacted with an aryl or vinyl halide to produce the aryl or vinyl anion via so-called halogen-metal exchange process, which reacted with internal carbonyl group to afford cyclized product in good yield.

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页码：6139 / 6142

页数：4

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