SYNTHESIS AND CRYSTAL-STRUCTURE OF 2 STEREOCHEMICAL ISOMERS OF THE TRANS-DICHLORO(1,4,8,11-TETRAAZACYCLOTETRA-DECANE)CHROMIUM(III) CATION

被引：19

作者：

FLORESVELEZ, LM

SOSARIVADENEYRA, J

SOSATORRES, ME ^{[1
]}

ROSALESHOZ, MJ

TOSCANO, RA

机构：

[1] NATL AUTONOMOUS UNIV MEXICO,FAC QUIM,DIV ESTUDIOS POSGRAD,CIUDAD UNIV,MEXICO CITY 04510,DF,MEXICO

[2] NATL AUTONOMOUS UNIV MEXICO,INST QUIM,MEXICO CITY 04510,DF,MEXICO

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1991年 / 12期

关键词：

D O I：

10.1039/dt9910003243

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two stereoisomers of the cationic trans-[Cr(cyclam)Cl2]+ complex (cyclam = 1,4,8,11-tetraazacyclotetradecane) were prepared and isolated as the nitrate and tetrachlorozincate salts and their structures determined by X-ray diffraction studies of the monoclinic crystals of the nitrate salt, a = 6.480(2), b = 18.862(12), c = 13.628(6) angstrom, beta = 100.28(3)-degrees, and tetragonal crystals for the tetrachlorozincate salt, a = 16.377(4), c = 6.821(2) angstrom. The two complexes show an octahedral geometry about the metal atoms with the RSSR configuration but with differences in the conformations of the six-membered rings.

引用

页码：3243 / 3247

页数：5

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