A NEW ALPHA-HALOGLYCINE TEMPLATE FOR THE ASYMMETRIC-SYNTHESIS OF AMINO-ACID DERIVATIVES

被引：19

作者：

BADRAN, TW

EASTON, CJ

HORN, E

KOCIUBA, K

MAY, BL

SCHLIEBS, DM

TIEKINK, ERT

机构：

[1] UNIV ADELAIDE,DEPT CHEM,GPO BOX 498,ADELAIDE,SA 5001,AUSTRALIA

[2] NATL CHEM LAB,DEPT CHEM,DIV CHEM ANAL & STAND,TSUKUBA,IBARAKI 305,JAPAN

来源：

TETRAHEDRON-ASYMMETRY | 1993年 / 4卷 / 02期

关键词：

D O I：

10.1016/S0957-4166(00)82336-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of (S)-N,N-diacylvalylglycine anhydride with N-bromosuccinimide afforded the corresponding alpha-bromoglycine derivative, which reacted diastereoselectively with allyltributyltin and deuterium over palladium chloride to give the corresponding alpha-allyl- and alpha-deuterio-glycine derivatives, respectively.

引用

页码：197 / 200

页数：4

共 21 条

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