CALCULATING STANDARD DEVIATIONS AND CONFIDENCE-INTERVALS WITH A UNIVERSALLY APPLICABLE SPREADSHEET TECHNIQUE

被引:434
作者
KRAGTEN, J
机构
关键词
NUMERICAL METHOD; ERROR PROPAGATION; ESTIMATED DEGREES OF FREEDOM; STANDARD DEVIATION; CONFIDENCE INTERVAL;
D O I
10.1039/an9941902161
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A quick and universally applicable spreadsheet method is outlined for the calculation of standard deviations based on the general formula for error propagation: S-R(2) = (partial derivative R/partial derivative X)(2) S-x(2) + (partial derivative R/partial derivative Y)(2) S-y(2) + (partial derivative R/partial derivative Z)(2) S-z(2) + ... With this method, standard deviations are calculated numerically without violating the condition of mutual independence, with a substantial time gain and with no risk of calculating errors. Satterthwaite's approximation of the degrees of freedom is a logical extension of the technique with which confidence intervals can be easily established. Direct insight is obtained about the separate contributions of the different error sources.
引用
收藏
页码:2161 / 2165
页数:5
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