SELECTIVE OXIDATION OF PRIMARY HYDROXY-GROUPS IN PRIMARY-SECONDARY DIOLS

被引:105
作者
SIEDLECKA, R [1 ]
SKARZEWSKI, J [1 ]
MLOCHOWSKI, J [1 ]
机构
[1] WROCLAW TECH UNIV,INST ORGAN & PHYS CHEM,PL-50370 WROCLAW,POLAND
关键词
D O I
10.1016/0040-4039(90)80102-R
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The two-phase oxidation of primary-secondary diols with sodium hypochlorite, mediated by TEMPO, brings about selective oxidation at the primary position. Such 5 diols are oxidized to the corresponding hydroxyaldehydes. © 1990.
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页码:2177 / 2180
页数:4
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