MICROEMULSION POLYMERIZATION OF STYRENE - A STUDY USING PULSED LASER INITIATION

被引：35

作者：

HOLDCROFT, S ^{[1
]}

GUILLET, JE ^{[1
]}

机构：

[1] UNIV TORONTO,DEPT CHEM,TORONTO M5S 1A1,ONTARIO,CANADA

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 1990年 / 28卷 / 07期

关键词：

D O I：

10.1002/pola.1990.080280714

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Microemulsions of styrene were polymerized using pulsed UV lasers. Molecular weights of the polystyrene produced were linearly dependent on the time interval between pulses when the number of photons absorbed per mL of microemulsion was ca. 5 × 1015. In contrast, laser pulses with much higher intensity produced polymers with molecular weights which were nonlinear with laser repetition rate. Copyright © 1990 John Wiley & Sons, Inc.

引用

页码：1823 / 1829

页数：7

共 18 条

[11] POLYMERIZATION OF OIL-IN-WATER MICROEMULSIONS - POLYMERIZATION OF STYRENE AND METHYL-METHACRYLATE [J].

JAYAKRISHNAN, A ;

SHAH, DO .

JOURNAL OF POLYMER SCIENCE PART C-POLYMER LETTERS, 1984, 22 (01) :31-38

[12] CHARACTERISTICS OF MICROEMULSION POLYMERIZED STYRENE WITH WATER-SOLUBLE VERSUS OIL-SOLUBLE INITIATORS [J].

JOHNSON, PL ;

GULARI, E .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1984, 22 (12) :3967-3982

[13] PHOTOINITIATED POLYMERIZATION OF STYRENE IN MICROEMULSIONS [J].

KUO, PL ;

TURRO, NJ ;

TSENG, CM ;

ELAASSER, MS ;

VANDERHOFF, JW .

MACROMOLECULES, 1987, 20 (06) :1216-1221

[14] INVERSE MICRO-EMULSION POLYMERIZATION [J].

LEONG, YS ;

CANDAU, F .

JOURNAL OF PHYSICAL CHEMISTRY, 1982, 86 (13) :2269-2271

[15] FLUORESCENCE PROBE STUDY OF THE INTERACTION BETWEEN PYRENE AND MICRO-EMULSION POLYMERIZED STYRENE [J].

LIANOS, P .

JOURNAL OF PHYSICAL CHEMISTRY, 1982, 86 (11) :1935-1937

[16]

OLAJ OF, 1987, MAKROMOL CHEM, V188, P1689

[17] POLYMERIZATION IN WATER-IN-OIL MICRO-EMULSION SYSTEMS .1. [J].

STOFFER, JO ;

BONE, T .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1980, 18 (08) :2641-2648

[18] EMULSION POLYMERIZATION - INITIATION OF POLYMERIZATION IN MONOMER DROPLETS [J].

UGELSTAD, J ;

ELAASSER, MS ;

VANDERHOFF, JW .

JOURNAL OF POLYMER SCIENCE PART C-POLYMER LETTERS, 1973, 11 (08) :503-513

← 1 2 →