SYNTHESIS AND NUCLEOPHILIC DISPLACEMENT-REACTIONS OF NOVEL (ETA-6-2-CHLORO-3-METHOXYESTRONE)(ETA-5-CYCLOPENTADIENYL)RUTHENIUM HEXAFLUOROPHOSPHATES

被引：18

作者：

MORIARTY, RM ^{[1
]}

GUO, L ^{[1
]}

KU, Y ^{[1
]}

GILARDI, R ^{[1
]}

机构：

[1] USN,RES LAB,STRUCT MATTER LAB,WASHINGTON,DC 20375

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1990年 / 24期

关键词：

D O I：

10.1039/c39900001765

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The alpha and beta-stereoisomeric title compounds were synthesized and each stereoisomer underwent clean nucleophilic displacement with -OMe, pyrrolidine, malonate and ethylamine.

引用

页码：1765 / 1765

页数：1

共 5 条

[1]

KOIGAWA T, 1986, ENDOCRINOL JAPON, V33, P221

[2] A NEW METHOD FOR INDOLE FUNCTIONALIZATION - NUCLEOPHILIC DISPLACEMENT-REACTIONS OF [ETA-6-(4-CHLOROINDOLE OR 5-CHLOROINDOLE)](ETA-5-CYCLOPENTADIENYL)RUTHENIUM(II) HEXAFLUOROPHOSPHATES [J].

MORIARTY, RM ;

KU, YY ;

GILL, US .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (19) :1493-1494

[3] (CYCLOPENTADIENYL)RUTHENIUM COMPLEXES OF 3-METHOXYESTRONE - A HIGH-FIELD NMR AND X-RAY CRYSTALLOGRAPHIC STUDY [J].

MORIARTY, RM ;

KU, YY ;

GILL, US ;

GILARDI, R ;

PERRIER, RE ;

MCGLINCHEY, MJ .

ORGANOMETALLICS, 1989, 8 (04) :960-967

[4]

MORIARTY RM, 1988, ORGANOMETALLICS, V7, P661

[5]

SANTANIELLO E, 1981, J CHEM SOC CHEM COMM, P217

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