ELECTRON-TRANSFER AND ION-PAIRING .20. 2-STEP REDUCTION OF TETRA(2'-PYRIDYL)PYRAZINE UNDER APROTIC CONDITIONS AS WELL AS IN SOLUTIONS CONTAINING LI+ AND NA+ CONDUCTING SALT CATIONS

被引：17

作者：

BOCK, H

JACULI, D

机构：

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1991年 / 46卷 / 08期

关键词：

CYCLIC VOLTAMMETRY; APROTIC CONDITIONS; TETRA(2'-PYRIDYL)PYRAZINE; ION PAIR FORMATION;

D O I：

10.1515/znb-1991-0819

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cyclovoltammetric measurements of solutions containing the rather basic tetra-(2'pyridyl)pyrazine allow to detect even traces of water and thus can be used as a touchstone for aprotic (C(H)+ < 1 ppm) conditions. On exchange of the ''innocent'' tetrabutylammonium R4N+ as supporting electrolyte cation by ''interactive'' ones such as Li+ or Na+, considerable changes in the reduction potentials are observed due to ion pair formation.

引用

页码：1091 / 1097

页数：7

共 35 条

[1] STUDIES OF IONS AND ION PAIRS IN TETRAHYDROFURAN SOLUTION . ALKALI METAL SALTS OF TETRAPHENYLBORIDE
BHATTACH.DN
LEE, CL
SMID, J
SZWARE, M
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1965, 69 (02) : 608 - &
[2] ELECTRON-TRANSFER AND ION-PAIRING .12. [(BENZOSEMIQUINONE-18-CROWN-6).-LI+NA+].+ - A PARAMAGNETIC TRIPLE ION WITH 2 DIFFERENT COUNTER CATIONS
BOCK, H
HERRMANN, HF
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (19) : 7622 - 7624
[3] BOCK H, 1988, Z NATURFORSCH B, V43, P1247
[4] ELECTRON-TRANSFER AND ION-PAIR FORMATION .4. THE SPIN DISTRIBUTION IN ION-PAIRS OF 1-AMINOANTHRAQUINONE RADICAL-ANION AND ALKALI-METAL CATIONS
BOCK, H
HIERHOLZER, B
SCHMALZ, P
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1987, 26 (08): : 791 - 793
[5] ONE-ELECTRON TRANSFERS AND ION-PAIR FORMATIONS .11. ONE-ELECTRON REDOX REACTIONS OF 4-(1-PYRIDINIO)PHENOLATE BETAINE - ESR ENDOR CHARACTERIZATION OF ITS RADICAL IONS AND BATTERY EFFECT
BOCK, H
HERRMANN, HF
[J]. HELVETICA CHIMICA ACTA, 1989, 72 (06) : 1171 - 1185
[6] ISOLATION AND STRUCTURE OF [(FLUORENONE.-)(NA+(DME)2)]2-A TOUCHSTONE FOR RADICAL CONTACT ION-PAIRS
BOCK, H
HERRMANN, HF
FENSKE, D
GOESMANN, H
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1988, 27 (08): : 1067 - 1069
[7] BOCK H, 1991, Z NATURFORSCH B, V46, P326
[8] RADICAL IONS .59. RADICAL ANION-SUBSTITUTED CROWN ETHERS AS CAGES FOR METAL-CATIONS
BOCK, H
HIERHOLZER, B
VOGTLE, F
HOLLMANN, G
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1984, 23 (01): : 57 - 58
[9] RADICAL IONS .63. OXIDATION REACTIONS WITH NAKED PERMANGANATE IONS UNDER APROTIC CONDITIONS
BOCK, H
JACULI, D
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1984, 23 (04): : 305 - 307
[10] STRUCTURES OF PERTURBED PI-SYSTEMS .3. TETRAPHENYLETHYLENEDISODIUM - THE BAND-STRUCTURE OF THE CC SINGLY BONDED, TWISTED (C6H5)2C CARBANIONS
BOCK, H
RUPPERT, K
FENSKE, D
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1989, 28 (12): : 1685 - 1688

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