STANDARD QUANTITIES IN CHEMICAL THERMODYNAMICS - FUGACITIES, ACTIVITIES, AND EQUILIBRIUM-CONSTANTS FOR PURE AND MIXED PHASES (IUPAC RECOMMENDATIONS 1994)

被引:57
作者
EWING, MB
LILLEY, TH
OLOFSSON, GM
RATZSCH, MT
SOMSEN, G
机构
关键词
D O I
10.1351/pac199466030533
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The standard chemical potential mu is defined in terms of a specified state of aggregation, a specified temperature and a specified standard pressure. Other s thermodynamic quantities are obtained from mu by the usual mathematical operations. In this report definitions are given for the standard chemical potential of a substance B in the following states of aggregation: gas phase whether pure or mixed, condensed phase pure or mixed, solvent substance in solution, and solute substance in solution. Fugacities and virial coefficients are introduced in the discussion of gases and activity, activity coefficients, and osmotic coefficients in the discussion of condensed phases. Expressions for the standard equilibrium constant are given for a reaction in the gas phase, in a condensed phase and in a solution. Some numerical examples are given and relative magnitudes of various terms in the equations are illustrated.
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页码:533 / 552
页数:20
相关论文
共 3 条
[1]  
1980, ISO3181980E
[2]  
1988, QUANTITIES UNITS SYM
[3]  
1982, PURE APPL CHEM, V54, P1239