PROPELLANES .10. BIS(PROPELLANES) AND TRIS(PROPELLANES) FROM METHYLBENZENES - 1,2-3,4-5,6-TRIS(8',11'-DIOXA[4.3.3]PROPELLA(3',4'))BENZENE

被引：8

作者：

JAMROZIK, J

ZESLAWSKI, W

机构：

来源：

CHEMISCHE BERICHTE | 1994年 / 127卷 / 12期

关键词：

PROPELLANES; BIS- AND TRIS-; POLYCYCLIC COMPOUNDS; HEXAMETHYLBENZENE;

D O I：

10.1002/cber.19941271217

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of the title tris(propellane) 17, derived from hexamethylbenzene, and bis(propellane) 12 is reported. Some aspects of the conformation of the compounds 12 and 17 are studied by H-1-NMR spectroscopy. Compound 17 exists as an equilibrium of two conformers with C-3 and C-1 symmetry. In the case of propellane 10, the formation of an isomeric bispirane compound is discussed.

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页码：2471 / 2474

页数：4

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