TRANSITION-STATE RESONANCES IN COLLINEAR (H-, H-2) COLLISIONS

被引：42

作者：

MAHAPATRA, S ^{[1
]}

SATHYAMURTHY, N ^{[1
]}

KUMAR, S ^{[1
]}

GIANTURCO, FA ^{[1
]}

机构：

[1] UNIV ROME,DEPT CHEM,I-00185 ROME,ITALY

来源：

CHEMICAL PHYSICS LETTERS | 1995年 / 241卷 / 03期

关键词：

D O I：

10.1016/0009-2614(95)00633-F

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The possibility of reactive scattering resonances in collinear (H-, H-2) collisions is examined by computing the transition state spectra obtained by Fourier transforming temporal autocorrelation functions for wavepackets placed initially in the transition state region of the ab initio potential energy surface for the system. The nature of the resonances is investigated by computing the corresponding eigenfunctions and their lifetimes.

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页码：223 / 228

页数：6

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