METHYLENOMYCIN-B - REVISED STRUCTURE AND TOTAL SYNTHESES

被引:45
作者
JERNOW, J
TAUTZ, W
ROSEN, P
WILLIAMS, TH
机构
[1] Chemical Research Department, Hoffmann-La Roche Inc., Nutley
关键词
D O I
10.1021/jo01337a049
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Starting from 2,3-dimethylcyclopent-2-en-l-one (4), it has been shown that methylenomycin B is not the epoxide 2 as reported, but rather 2,3-dimethyl-5-methylenecyclopent-2-en-l-one (3). © 1979, American Chemical Society. All rights reserved.
引用
收藏
页码:4212 / 4213
页数:2
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