LIGAND-COUPLING REACTIONS OF HYPERVALENT SPECIES

被引：178

作者：

OAE, S ^{[1
]}

UCHIDA, Y ^{[1
]}

机构：

[1] OSAKA INST TECHNOL,DEPT APPL CHEM,ASAHI KU,OSAKA 535,JAPAN

来源：

ACCOUNTS OF CHEMICAL RESEARCH | 1991年 / 24卷 / 07期

关键词：

D O I：

10.1021/ar00007a003

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The basic concept of ligand coupling within hypervalent species has been introduced. In nearly all cases,retention of configuration of coupling ligands has been observed. This indicates a mechanism involving the concerted front-side coupling between an axial and an equatorial ligand. The stereochemical nature of the reaction has been used to diagnose the occurrence of ligand coupling, whenever there are some stereochemical data available. © 1991, American Chemical Society. All rights reserved.

引用

页码：202 / 208

页数：7

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