A PULSED DISCHARGE SOURCE OF TRANSIENTS FOR MATRIX-ISOLATION SPECTROSCOPY

被引:44
作者
THOMA, A
WURFEL, BE
SCHLACHTA, R
LASK, GM
BONDYBEY, VE
机构
[1] TECH UNIV MUNICH,INST PHYS & THEORET CHEM,LICHTENBERGSTR 4,W-8046 GARCHING,GERMANY
[2] OHIO STATE UNIV,DEPT CHEM,COLUMBUS,OH 43210
关键词
D O I
10.1021/j100197a019
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We have combined an electrical discharge-pulsed jet source with matrix isolation spectroscopy to produce matrices of high optical quality that contain large concentrations of isolated transient species. In our initial studies, we have been able to produce a variety of transient species, including the N atom, C2-, CS, C2F3, and CNN.
引用
收藏
页码:7231 / 7235
页数:5
相关论文
共 30 条
[1]   SYNCHRONIZED FLASH-PHOTOLYSIS AND PULSE DEPOSITION IN MATRIX-ISOLATION EXPERIMENTS [J].
ALLAMANDOLA, LJ ;
LUCAS, D ;
PIMENTEL, GC .
REVIEW OF SCIENTIFIC INSTRUMENTS, 1978, 49 (07) :913-918
[2]   LASER EXCITED FLUORESCENCE STUDIES OF MATRIX ISOLATED C2- [J].
BONDYBEY, V ;
NIBLER, JW .
JOURNAL OF CHEMICAL PHYSICS, 1972, 56 (09) :4719-&
[3]   HIGH-RESOLUTION FOURIER-TRANSFORM INFRARED-SPECTRA (CS)-C-12-S-32, (CS)-C-12-S-3), (CS)-C-12-S-34, AND (CS)-C-13-S-32 [J].
BURKHOLDER, JB ;
LOVEJOY, ER ;
HAMMER, PD ;
HOWARD, CJ .
JOURNAL OF MOLECULAR SPECTROSCOPY, 1987, 124 (02) :450-457
[4]   THE VALENCE ISOELECTRONIC MOLECULES CCO, CNN, SICO, AND SINN IN THEIR TRIPLET GROUND-STATES - THEORETICAL PREDICTIONS OF STRUCTURES AND INFRARED-SPECTRA [J].
DEKOCK, RL ;
GREV, RS ;
SCHAEFER, HF .
JOURNAL OF CHEMICAL PHYSICS, 1988, 89 (05) :3016-3027
[5]   SPECTROSCOPY OF JET-COOLED IONS AND RADICALS [J].
ENGELKING, PC .
CHEMICAL REVIEWS, 1991, 91 (03) :399-414
[6]   SPECTRA AND STRUCTURE OF GASEOUS ORGANIC FREE-RADICALS - A STATUS-REPORT [J].
FOSTER, SC ;
MILLER, TA .
JOURNAL OF PHYSICAL CHEMISTRY, 1989, 93 (16) :5986-5999
[8]   SPECTROSCOPIC STUDY OF THE PHOTOLYSIS OF DIAZOMETHANE IN SOLID NITROGEN [J].
GOLDFARB, TD ;
PIMENTEL, GC .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1960, 82 (08) :1865-1868
[9]   A NEW SPECTRUM ASSOCIATED WITH DIATOMIC CARBON [J].
HERZBERG, G ;
LAGERQVIST, A .
CANADIAN JOURNAL OF PHYSICS, 1968, 46 (21) :2363-+
[10]  
Herzberg G., 1971, SPECTRA STRUCTURE SI