MEDIUM EFFECTS ON NMR AND THERMODYNAMIC PROPERTIES OF 1,1,2,2-TETRABROMOFLUOROETHANE

被引：28

作者：

GOVIL, G

BERNSTEIN, HJ

机构：

[1] Division of Pure Chemistry, National Research Council, Ottawa

来源：

JOURNAL OF CHEMICAL PHYSICS | 1968年 / 48卷 / 01期

关键词：

D O I：

10.1063/1.1667917

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Chemical shifts, coupling constant, free energy, and free energy of activation for 1,1,2,2-tetrabromofluoroethane have been found to depend on temperature and solvent. The results can be explained qualitatively using the reaction-field" model. Vapor-phase values for the different thermodynamic and NMR properties of the molecule have been estimated. Theory for calculating NMR spectra of two exchanging AX systems has been presented."

引用

页码：285 / +

页数：1

共 19 条

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