LOW-TEMPERATURE FLOW NMR INVESTIGATION OF THE TRANSIENT INTERMEDIATE IN THE NUCLEOPHILIC AROMATIC-SUBSTITUTION OF 2,4,6-TRINITROANISOLE BY NORMAL-BUTYLAMINE

被引：37

作者：

FYFE, CA

DAMJI, SWH

KOLL, A

机构：

[1] Guelph Campus, University of Guelph, Gueiph, Ontario

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1979年 / 101卷 / 04期

关键词：

D O I：

10.1021/ja00498a025

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

High-resolution flow NMR has been used at low temperatures to detect and to characterize the transient intermediate δ complex on the reaction pathway in the nucleophilic aromatic substitution reaction of 2, 4, 6-trinitroanisole by n-butyl-amine in a solvent mixture of 50% Me2SO-5Q% MeOH. © 1979, American Chemical Society. All rights reserved.

引用

页码：951 / 955

页数：5

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