STEREOCHEMICAL DEPENDENCE OF THE VICINAL C-13-N-14 COUPLING-CONSTANT AS A CONSTITUTIONAL PROBE

被引：7

作者：

VALCKX, LA ^{[1
]}

BORREMANS, FAM ^{[1
]}

BECU, CE ^{[1
]}

DEWAELE, RHK ^{[1
]}

ANTEUNIS, MJO ^{[1
]}

机构：

[1] STATE UNIV GHENT,DEPT ORGAN CHEM,NMR SPECTROSCOPY LAB,B-9000 GHENT,BELGIUM

来源：

ORGANIC MAGNETIC RESONANCE | 1979年 / 12卷 / 05期

关键词：

D O I：

10.1002/mrc.1270120511

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The magnitudes of 13C14N coupling constants have been measured in 12 rigid or anancomeric (biased) tetraalkylammonium iodides. The one‐bond coupling is typical for the degree of substitution of the carbon atom and the geminal coupling is very small. Vicinal couplings depend on the dihedral angle and other factors. Copyright © 1979 Heyden & Son Ltd.

引用

页码：302 / 305

页数：4

共 29 条

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