SEGMENTAL ADSORPTION ENERGY AND PHASE-BEHAVIOR OF FILLED POLYMER BLENDS

被引：17

作者：

GRITSENKO, OT ^{[1
]}

NESTEROV, AE ^{[1
]}

机构：

[1] ACAD SCI UKSSR,INST MACROMOLEC CHEM,KIEV 252160,UKRAINE,USSR

来源：

EUROPEAN POLYMER JOURNAL | 1991年 / 27卷 / 4-5期

关键词：

D O I：

10.1016/0014-3057(91)90206-4

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The parameters of segmental adsorption energy for poly(methyl methacrylate) and poly(vinyl acetate) in solvents of various thermodynamic qualities have been determined. Selective adsorption from PMMA-PVAc blend and its influence on the phase behaviour of filled films have been investigated. It is supposed that the shift of cloud-point curves correlates with the magnitude of adsorption of one of the components on the filler surface, which is in turn determined by the magnitude of the segmental adsorption energy.

引用

页码：455 / 459

页数：5

共 17 条

[1] THE IMPORTANCE OF ENTHALPIC INTERACTIONS IN POLYMERIC SYSTEMS [J].

BARLOW, JW ;

PAUL, DR .

POLYMER ENGINEERING AND SCIENCE, 1987, 27 (20) :1482-1494

[2] THE PHASE-BEHAVIOR OF TERNARY BLENDS CONTAINING POLYCARBONATE, PHENOXY, AND POLYCAPROLACTONE [J].

CHRISTIANSEN, WH ;

PAUL, DR ;

BARLOW, JW .

JOURNAL OF APPLIED POLYMER SCIENCE, 1987, 34 (02) :537-548

[3]

FLEER GJ, 1983, ADSORPTION SOLUTION

[4]

GRITSENKO OT, 1987, VYSOKOMOL SOEDIN B, V29, P611

[5] DISPLACEMENT OF POLYMERS BY DISPLACERS .1. POLYSTYRENE AT THE SILICA SURFACE [J].

KAWAGUCHI, M ;

CHIKAZAWA, M ;

TAKAHASHI, A .

MACROMOLECULES, 1989, 22 (05) :2195-2199

[6]

Kiselev A.V., 1975, INFRARED SPECTRA SUR

[7]

KISELEV AV, 1968, KOLLOID ZH, V30, P386

[8]

NESTEROV AE, 1984, HDB PHYSICAL CHEM PO, V5

[9]

NESTEROV AE, 1988, DOKL AKAD NAUK SSSR+, V229, P656

[10]

NESTEROV AY, 1987, VYSOKOMOL SOEDIN A+, V29, P1252

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