CRYSTALLOGRAPHIC AND SPECTROSCOPIC ASSESSMENT OF CHELATE-STABILIZED ARYL HALIDE-COMPLEXES AT A 7-COORDINATE D4 MOLYBDENUM CENTER

被引：17

作者：

HARRISON, R

ARIF, AM

WULFSBERG, G

LANG, R

JU, T

KISS, G

HOFF, CD

RICHMOND, TG

机构：

[1] UNIV UTAH,DEPT CHEM,SALT LAKE CITY,UT 84112

[2] MIDDLE TENNESSEE STATE UNIV,DEPT CHEM,MURFREESBORO,TN 37132

[3] UNIV MIAMI,DEPT CHEM,CORAL GABLES,FL 33124

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 18期

关键词：

D O I：

10.1039/c39920001374

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new series of chelate stabilized aryl halide coordination complexes of molybdenum are prepared by a novel oxidative addition strategy; quantitative equilibrium measurements suggest that the structure of the chelate ring, rather than the identity of the halide (X = Cl, Br, I), controls the strength of aryl halide binding in these complexes.

引用

页码：1374 / 1376

页数：3

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