SYNTHESIS OF 1,4-(1,1'-FERROCENEDIYL)-1,3-BUTADIENE - A DIENO-FERROCENOPHANE

被引：10

作者：

ERICKSON, MS ^{[1
]}

FRONCZEK, FR ^{[1
]}

MCLAUGHLIN, ML ^{[1
]}

机构：

[1] LOUISIANA STATE UNIV,DEPT CHEM,BATON ROUGE,LA 70803

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 02期

关键词：

D O I：

10.1016/S0040-4039(00)60545-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Excess sodium borohydride in methanol quantitatively reduces 1,4-(1,1'-ferrocenediyl)-1,4-butanedione to 1,4-(1,1'-ferrocenediyl)-1,4-butanediol which in dilute benzene undergoes tandem dehydration catalyzed by p-toluenesulfonic acid to 1,4-(1,1'-ferrocenediyl)-1,3-butadiene in a 61% yield. X-ray crystal structures of 1,4-(1,1'-ferrocenediyl)-1,3-butadiene and 1,4-(1,1'-ferrocenediyl)-1,4-butanedione are compared.

引用

页码：197 / 198

页数：2

共 3 条

[1] SYNTHESIS OF 1,4-DIKETONES BY OXIDATIVE COUPLING OF KETONE ENOLATES WITH CUCL2 [J].