SYNTHESIS AND CHARACTERIZATION OF BOTH ENANTIOMERS OF A CHIRAL C-60 DERIVATIVE WITH C-2 SYMMETRY

被引：33

作者：

MAGGINI, M

SCORRANO, G

BIANCO, A

TONIOLO, C

PRATO, M

机构：

[1] UNIV TRIESTE,DIPARTIMENTO SCI FARMACEUT,I-34127 TRIESTE,ITALY

[2] CNR,CTR MECCANISMI REAZ ORGAN,I-35131 PADUA,ITALY

[3] CNR,CTR STUDIO BIOPOLIMERI,DIPARTIMENTO CHIM ORGAN,I-35131 PADUA,ITALY

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 16期

关键词：

D O I：

10.1016/0040-4039(95)00361-F

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The addition of chiral diamines to C-60 allows the synthesis of the two enantiomers of a chiral C-60 derivative with C-2 symmetry. The circular dichroism spectra of the two isomers show a very intense chirospectroscopic response.

引用

页码：2845 / 2846

页数：2

共 7 条

[1]

Vasella, Uhlmann, Waldraff, Diederich, Thilgen, Angew. Chem., Int. Ed. Engl., 31, pp. 1388-1390, (1992)

[2]

Hawkins, Meyer, Science, 260, pp. 1918-1920, (1993)

[3]

Hawkins, Meyer, Nambu, J. Am. Chem. Soc., 115, pp. 9844-9845, (1993)

[4]

Hawkins, Nambu, Meyer, J. Am. Chem. Soc., 116, pp. 7642-7645, (1994)

[5]

Wilson, Wu, Kaprinidis, Schuster, J. Org. Chem., 58, pp. 6548-6549, (1993)

[6]

Kampe, Egger, Vogel, Angew. Chem., Int. Ed. Engl., 32, pp. 1174-1176, (1993)

[7]

Benson, Cai, Colon, Haiza, Tokles, Snyder, J. Org. Chem., 53, pp. 5335-5341, (1988)

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