Novel insertion of dimethylsilanone into an Yb-N bond and molecular structure of the insertion product [{Yb(eta(2)-C(3)N(2)HMe(2)-3,5)(mu-eta(1):eta(2)-OSiMe(2)C(3)N(2)HMe(2)-3,5)(eta-C(5)H(4)Me)}(2)]

被引：37

作者：

Zhou, XG

Ma, HZ

Huang, XY

You, XZ

机构：

[1] NANJING UNIV,INST COORDINAT CHEM,NANJING 210008,PEOPLES R CHINA

[2] NANJING UNIV,NATL KEY LAB COORDINAT CHEM,NANJING 210008,PEOPLES R CHINA

[3] ANHUI NORMAL UNIV,INST ORGAN CHEM,WUHU 241000,ANHUI,PEOPLES R CHINA

[4] STATE KEY LAB STRUCT CHEM,FUZHOU 350002,PEOPLES R CHINA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 24期

关键词：

D O I：

10.1039/C39950002483

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

When [Yb(C(3)N(2)HMe(2)-3,5)(2)(C(5)H(4)Me)] (C(3)N(2)H(2)Me(2)-3,5 = 3,5-dimethylpyrazole) is recrystallized by slow diffusion of hexane into a thf solution which contains a small amount of dimethylsilicone grease, it is converted into to the unexpected complex [{Yb(eta(2)-C(3)N(2)HMe(2)-3,5)(nu-eta(1) : eta(2)-OSiMe(2)C(3)N(2)HMe(2)-3,5)(eta-C(5)H(4)Me)}(2)] indicating a novel Me(2)SiO insertion reaction.

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页码：2483 / 2484

页数：2

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