OXYFLUORINATED MICROPOROUS COMPOUNDS .11. SYNTHESIS AND CRYSTAL-STRUCTURE OF ULM-10 - THE 1ST BIDIMENSIONAL MIXED-VALENCE IRON FLUOROPHOSPHATE WITH INTERCALATED ETHYLENEDIAMINE

被引：62

作者：

CAVELLEC, M ^{[1
]}

RIOU, D ^{[1
]}

FEREY, G ^{[1
]}

机构：

[1] UNIV MAINE,FLUORURES LAB,CNRS,URA 449,AVE OLIVIER MESSAIEN,F-72017 LE MANS,FRANCE

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 1994年 / 112卷 / 02期

关键词：

D O I：

10.1006/jssc.1994.1331

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first oxyfluorinated iron(II, III) phosphate (Fe3+Fe2+F2 (HPO4)2(H2O)2, ethylenediamine] with an open structure has been synthesized. It is triclinic (P-1 (No. 2), a = 5.174(2) angstrom, b = 7.518(2) angstrom, c = 8.773(3) angstrom, alpha = 108.37(1)-degrees, beta = 97.33(2)-degrees, gamma = 109.86(2)-degrees, Z = 1). Its bidimensional structure contains chains of Fe(II) and Fe(III) octahedra, arranged in an ordered way and linked to each other by phosphate groUpS. (C) 1994 Academic Press, Inc.

引用

页码：441 / 442

页数：2

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