ZOANTHID STEROLS

被引:38
作者
GUPTA, KC
SCHEUER, PJ
机构
[1] Department of Chemistry, University of Hawaii Honolulu
基金
美国国家科学基金会;
关键词
D O I
10.1016/0039-128X(69)90043-9
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Our fragmentary and out-of-date knowledge of coelenterate sterols has prompted us to examine in detail the sterols of three zoanthids, Zoanthus confertus from Hawaii, Palythoa tuberculosa from Eniwetok and a Tahitian Palythoa sp. The sterol mixture of Zoanthus confertus consists of four components, 24β-methylcholesta-5,22-dien-3β-ol, choiest-5-en-3β-ol, 24-methyl-cholest-5-en-3β-ol and 24-methylenecholesta-5,24(28)-dien-3β-ol. The sterol mixture isolated from Palythoa tuberculosa is apparently identical with the previously reported palysterol from P. mammilosa. Its components are 24β-methylcholest-5-en-3β-ol, 24β-methy1cholesta-5, 22-dien-3β-ol, gorgosterol of as yet unknown structure, cholest-5-en-3β-ol and 24-ethylcholest-5-en-3β-ol. 24-Methylenecholesta-5, 24(28)-dien-3β-ol was recognized as the sole sterol in the Palythoa sp. from Tahiti. This study affords for the first time a detailed knowledge of the sterol mixtures in three members of the coelenterate family Zoanthidae. © 1968.
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页码:343 / &
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