STEREOSPECIFICITY OF ALKOXYMERCURATION OF ALLENES

被引：46

作者：

BACH, RD

机构：

[1] School of Chemistry, University of Minnesota, Minneapolis

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1969年 / 91卷 / 07期

关键词：

D O I：

10.1021/ja01035a029

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The ethoxymercuration of optically active 1,2-cyclononadiene with a series of mercuric salts is described. Evidence is presented for the existence of a mercurinium ion intermediate 2 and an allylic carbonium ion 3 which may be formed reversibly from 2. The stability of 2, and the relative stereospecificity of the reaction, is shown to be directly related to the mercuric salt utilized in the reaction. © 1969, American Chemical Society. All rights reserved.

引用

页码：1771 / &

共 46 条

[1]

BACH RD, 1968, TETRAHEDRON LETT, P5841

[2]

BACH RD, 1967, THESIS MASSACHUSETTS

[3]

BANNEY PJ, 1967, TETRAHEDRON LETT, P27

[4] MOLECULAR ORBITAL THEORY FOR OCTAHEDRAL AND TETRAHEDRAL METAL COMPLEXES [J].