HYDROLYSIS OF AMIDES - ELECTRONIC EFFECTS ON KINETICS AND MECHANISM OF THE BASIC HYDROLYSIS OF N-SUBSTITUTED BENZOYLPYRROLES

被引：23

作者：

CIPICIANI, A

LINDA, P

SAVELLI, G

机构：

[1] Dipartimento di Chimica, Universita di Perugia, Perugia

来源：

JOURNAL OF HETEROCYCLIC CHEMISTRY | 1979年 / 16卷 / 04期

关键词：

D O I：

10.1002/jhet.5570160411

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The hydroxide ion catalyzed hydrolysis of a series of N‐substituted benzoylpyrroles has been studied in water at 25°. Hammett treatment of data shows that substituents affect in a very similar way the rate of formation and of decomposition of the tetrahedral intermediate. Copyright © 1979 Journal of Heterocyclic Chemistry

引用

页码：673 / 675

页数：3

共 6 条

[1] STERIC AND ELECTRONIC EFFECTS IN HYDROLYSIS OF N-ACYLIMIDAZOLES AND N-ACYLIMIDAZOLIUM IONS
FEE, JA
FIFE, TH
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1966, 31 (07) : 2343 - &
[2] KERSHNER LD, 1971, J AM CHEM SOC, V93, P2014
[3] AN EXTENDED TABLE OF HAMMETT SUBSTITUENT CONSTANTS BASED ON THE IONIZATION OF SUBSTITUTED BENZOIC ACIDS
MCDANIEL, DH
BROWN, HC
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1958, 23 (03) : 420 - 427
[4] SUBSTITUENT EFFECTS IN THE ACID AND BASE HYDROLYSES OF AROMATIC AMIDES
MELOCHE, I
LAIDLER, KJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1951, 73 (04) : 1712 - 1714
[5] BASE-CATALYZED HYDROLYSIS OF N-ACYLPYRROLES - MEASURABLE ACIDITY OF A STEADY-STATE TETRAHEDRAL INTERMEDIATE
MENGER, FM
DONOHUE, JA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (02) : 432 - 437
[6] WOLFE RHD, 1971, J ORG CHEM, V36, P3870

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