ARE LATTICE MODELS VALID FOR FLUIDS WITH HYDROGEN-BONDS

被引：179

作者：

VEYTSMAN, BA ^{[1
]}

机构：

[1] PHYS CHEM INST,ODESSA 270080,USSR

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1990年 / 94卷 / 23期

关键词：

D O I：

10.1021/j100386a002

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A Flory-like approximation for a lattice model of fluid mixture with hydrogen bonds is proposed. The obtained excess free energy due to H bonds is consistent in the limiting cases with the asymptotics derived by Huyskens, but it is valid for the general case also. © 1990 American Chemical Society.

引用

收藏

页码：8499 / 8500

页数：2

相关论文

共 7 条

[1] PHASE EQUILIBRIA IN SOLUTIONS OF ROD-LIKE PARTICLES [J].

FLORY, PJ .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1956, 234 (1196) :73-89

[2] MOLECULAR-STRUCTURE OF LIQUID ALCOHOLS [J].

HUYSKENS, P .

JOURNAL OF MOLECULAR STRUCTURE, 1983, 100 (JUL) :403-414

[3]

HUYSKENS PL, 1988, J PHYS CHEM-US, V92, P5841

[4] PROPERTIES OF BINARY AND TERNARY MIXTURES IN THE VICINITIES OF DOUBLE CRITICAL-POINTS [J].

MALOMUZH, NP ;

VEITSMAN, BA .

PHYSICS LETTERS A, 1989, 136 (4-5) :239-244

[5] THERMODYNAMIC PROPERTIES OF ASSOCIATED SOLUTIONS [J].

MARSH, K ;

KOHLER, F .

JOURNAL OF MOLECULAR LIQUIDS, 1985, 30 (01) :13-55

[6] LATTICE THEORY OF BINARY FLUID MIXTURES - PHASE-DIAGRAMS WITH UPPER AND LOWER CRITICAL SOLUTION POINTS FROM A RENORMALIZATION-GROUP CALCULATION [J].

WALKER, JS ;

VAUSE, CA .

JOURNAL OF CHEMICAL PHYSICS, 1983, 79 (06) :2660-2676

[7] SOME INTERESTING NEW PHASE-DIAGRAMS IN HYDROGEN-BONDED LIQUID-MIXTURES [J].

WHEELER, JC ;

ANDERSEN, GR .

JOURNAL OF CHEMICAL PHYSICS, 1980, 73 (11) :5778-5785